Angel, Wynter could definitely be a good friend for Maddie, as they both love animals. Plus, it would be good for Maddie to have a girl friend her age. Most of the older students she interacts with are due to Theo's influence, but she and Shade might connect over Quidditch, since Maddie is very fond of the sport and flying in general.
Amberlee, I can see Maddie being fond of Cadance, and probably forcing her to have tea parties and such. While Maddie would enjoy being doted on, she has little love for her family outside of Theo, so would probably try to teach Cadance how to rebel a bit.